Lapprand A, Bonnot A, Knorr M, Rousselin Y, Kubicki MM, Fortin D, Harvey PD. Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect. Chem Commun (Camb). 2013;49(78):8848–50.
Abstract
A unique pentanuclear cluster within a zeolite-type polymer ([Cu5(μ4-Br)(μ3-Br)2(μ2-Br)2](μ2-MeSPr)3)n (1; void space >81%) and a luminescent 1D ([Cu(μ3-I)]4(MeSPr)3)n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.
Last updated on 02/26/2023